Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2015 Electronic Supplementary Information Visible light-induced enhanced photoelectrochemical and photocatalytic studies of gold decorated SnO2 nanostructure Mohammad Mansoob Khan1¥, Sajid Ali Ansari1, Mohammad Ehtisham Khan1, Mohd Omaish Ansari1, Bong-Ki Min2 and Moo Hwan Cho1* 1School of Chemical Engineering, Yeungnam University, Gyeongsan-si, Gyeongbuk 712-749, South Korea. 2Center for Research Facilities, Yeungnam University, Gyeongsan-si, Gyeongbuk 712-749, South Korea. UV-vis diffuse reflectance spectra of Au-SnO2 nanocomposites and P-SnO2 100 P-SnO2 Au-SnO2 90 Reflectance (%R) 80 70 60 50 40 30 20 10 0 200 300 400 500 600 Wavelength (nm) 700 800 Fig. S1. UV-vis diffuse reflectance spectra of P-SnO2 and Au-SnO2 nanocomposite. 1 XRD patterns of the Au-SnO2 nanocomposite and P-SnO2 (220) 50 60 (311) 70 80 70 (321) (310) (112) (301) (002) 40 50 60 2 Theta (degree) (202) P-SnO2 (220) (200) 30 (211) 40 (101) 30 (200) 1000 500 250020 2000 1500 1000 500 0 20 Au-SnO2 * Planes of gold (111) 1500 (110) Intensity Intensity 2000 80 Fig. S2. XRD patterns of the Au-SnO2 nanocomposite and P-SnO2. The peaks marked with (*) represents the Au signals. Final output of Rietveld refinement indices for Au-SnO2 nanocomposite and P-SnO2 (a) (b) Fig. S3. Rietveld refinement indices for (a) Au-SnO2 nanocomposite and (b) P-SnO2. 2 TEM image of P-SnO2 nanoparticles Fig. S4. TEM image of P-SnO2 nanoparticles. Acquired HAADF of Au-SnO2 nanocomposite Fig. S5. Representative HAADF FE-TEM image of Au-SnO2 nanocomposite. EDX of Au-SnO2 nanocomposite Fig. S6. EDX of Au-SnO2 nanocomposite. 3 XPS spectra of P-SnO2 and Au-SnO2 nanocomposite P-SnO2 Au-SnO2 Intensity (a.u.) C 1s 294 292 290 288 286 284 282 Binding Energy (eV) 280 278 Fig. S7. XPS spectra of P-SnO2 and Au-SnO2 nanocomposite for C 1s peak. Stability of the Au-SnO2 nanocomposite Absorbance (a.u.) Au-SnO2 300 No absorption 400 500 600 nm 700 800 Fig. S8. Stability test of the Au-SnO2 nanocomposite. 4
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