1. Espiritual

ユミコア社・ソルビアス社製 触媒
Catalyst of Umicore・Solvias
この度、弊社では下記Umicore社・Solvias社製の触媒の販売を開始いたしました。
ご愛顧賜りますよう宜しくお願い申し上げます。
【Umicore社】 CXシリーズ（クロスカップリング用パラジウム触媒）
・触媒調製用の配位子フリーPd触媒。
・鈴木-宮浦カップリングやBuchwald-Hartwigアミノ化反応、Heck反応、熊田反応、ケトンのアリル化
反応など、Pd触媒を利用するカップリング反応に有用。
特徴
Chlorophenylallyl[1,3-bis(2,6-diisopropylphenyl)
imidazol-2-ylidene]palladium(II)
49023-20
500 mg
¥14,600
Chlorophenylallyl[1,3-bis(2,6-diisopropylphenyl)2-imidazolidinylidene]palladium(II)
49023-22
500 mg
[884879-23-6]
[884879-24-7]
Umicore No. 68 1844 4716
Umicore No. 30000 34527
CX32
CX31
Allylchloro[1,3-bis(2,6-diisopropylphenyl)imidazol2-ylidene]palladium(II)
49022-06
500 mg
¥14,600
Allylchloro[1,3-bis-(2,6-diisopropylphenyl)imidazol2-idinylidene]palladium(II)
49022-08
500 mg
[478980-01-7]
Umicore No. 68 1844 4018
Umicore No. 30000 34526
Dichloro(di-μ-chloro)bis[1,3-bis(2,6-diisopropylphenyl)
imidazol-2-ylidene]dipalladium(II)
49022-76
Cl
N
Cl
Pd
Cl
Pd
Cl
¥14,600
[478980-03-9]
CX21
N
¥14,600
500 mg
¥14,600
CX23
Allylchloro[1,3-bis-(2,4,6-trimethylphenyl)imidazol2-ylidene]palladium(II)
49022-10
500 mg
¥14,800
[444910-17-2]
[478980-04-0]
Umicore No. 68 1844 3519
Umicore No. 68 1844 4022
N
N
CX41
CX22
Bis(1,4-naphthoquinone)bis[1,3-bis(2,6-diisopropylphenyl)
imidazole-2-ylidene]dipalladium(0)
Bis(1,4-naphthoquinone)bis[1,3-bis(2,4,6-trimethylphenyl)
imidazol-2-ylidene]dipalladium(0)
49023-14
500 mg
¥14,600
49023-16
500 mg
¥14,600
[649736-75-4]
[467220-49-1]
Umicore No. 68 1844 4016
Umicore No. 68 1844 4019
CX11
CX12
その他Umicore社製 化合物
Bis(η5-2,4-dimethylpentadienyl)ruthenium(II)
49022-44
500 mg
(1,5-Cyclooctadiene)bis(2-methylallyl)ruthenium(II)
¥58,400
49022-56
500 mg
¥29,200
[85908-78-7]
[12289-94-0]
Umicore No. 68 1874 3834
Umicore No. 68 1874 2432
Ru
Bis(1,5-cyclooctadiene)tetra[μ-trifluoroacetato]
diruthenium(II) hydrate
49022-70
500 mg
Di(μ-chloro)dichlorobis(benzene)diruthenium(II)
¥78,300
Umicore No. 68 1874 2423
Umicore No. 68 1874 3540
500 mg
Di(μ-iodo)diiodobis(p-cymene)diruthenium(II)
¥3,600
BF4
500 mg
¥19,400
[90614-07-6]
Umicore No. 68 1874 1310
Umicore No. 68 1874 2621
49023-56
N
49022-96
[15529-49-4]
Trisacetonitrile(η5-2,4-dimethylpentadienyl)
ruthenium(II) tetrafluoroborate
N
¥15,600
[37366-09-9]
49022-94
N
500 mg
[93582-31-1]
Dichlorotris(triphenylphosphine)ruthenium(II)
Ru
49022-74
500 mg
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
¥71,400
49022-36
500 mg
¥28,200
[145271-55-2]
[35138-22-8]
Umicore No. 68 1874 3325
Umicore No. 68 1864 3025
Bis(1,5-cyclooctadiene)rhodium(I)
trifluoromethanesulfonate
49022-38
Bisnorbornadienerhodium(I) tetrafluoroborate
500 mg
¥18,400
49022-58
500 mg
¥26,400
[99326-34-8]
[36620-11-8]
Umicore No. 68 1864 3822
Umicore No. 68 1864 3627
Di(μ-chloro)dichlorobis(pentamethylcyclopentadiene)
dirhodium(III)
Di(μ-chloro)bis(norbornadiene)dirhodium(I)
49022-66
500 mg
¥13,200
49022-90
Cl
[12257-42-0]
Rh
Umicore No. 30000 34546
Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)
phosphine]palladium(II)
49022-40
500 mg
Cl
500 mg
¥18,000
[12354-85-7 ]
Cl
Rh
Cl
Umicore No. 68 1864 3033
Dichloro[1,1’-bis(di-tert-butylphosphino)ferrocene]
palladium(II)
¥15,400
49022-42
500 mg
¥14,200
[887919-35-9]
[95408-45-0]
Umicore No. 68 1844 5415
Umicore No. 30000 34532
Dichloro[1,1’-bis(diphenylphosphino)ferrocene]
palladium(II)
49022-78
500 mg
Dichloro[1,1’-Bis(diphenylphosphino)ferrocene]
palladium(II) acetone adduct
¥3,000
49022-80
500 mg
¥3,000
[72287-26-4]
[851232-71-8]
Umicore No. 68 1844 4114
Umicore No. 30000 36045
Dichloro[1,1’-Bis(diphenylphosphino)ferrocene]
palladium(II) dichloromethane adduct
49022-82
500 mg
Bis(tri-tert-butylphosphine)palladium(0)
¥3,000
49023-04
[95464-05-4]
500 mg
¥15,600
[53199-31-8]
P Pd P
Umicore No. 68 1844 4213
Dichlorobis[(di-tert-butyl)phenylphosphine]
palladium(II)
49023-64
500 mg
Umicore No. 30000 34529
Dichlorobis[(di-tert-butyl)(n-butyl)phosphine]
palladium(II)
¥15,400
49023-65
500 mg
¥15,400
[34409-44-4]
[1444507-24-7]
Umicore No. 68 1844 5517
Umicore No. 30000 36046
Tris(dibenzylideneacetone)dipalladium(0)
49023-62
Bis(1,5-cyclooctadiene)iridium(I) tetrafluoroborate
500 mg
¥4,600
Umicore No. 30000 34523
Umicore No. 30000 34535
500 mg
Di(μ-chloro)bis(1,5-cyclooctadiene)diiridium(I)
¥49,000
49022-64
¥6,600
[12112-67-3]
Umicore No. 68 1854 2015
Umicore No. 30000 34536
49023-06
500 mg
Di(μ-iodo)diiodobis(pentamethylcyclopentadienyl)
diiridium(III)
¥10,000
49023-08
I
Cl
Ir
Ir
Umicore No. 68 1854 3449
Cl
500 mg
[666826-16-0]
Di(μ-chloro)dichlorobis(pentamethylcyclopentadienyl)
diiridium(III)
Cl
¥50,600
[35138-23-9]
49022-34
Ir
500 mg
[51364-51-3]
Bis(1,5-cyclooctadiene)iridium(I)
tetrakis[3,5-bis(trifluoromethyl)phenyl]borate
Cl
49022-32
I
I
500 mg
¥17,000
[33040-12-9 ]
Ir
I
Umicore No. 68 1854 3533
Platinum(IV) oxide hydrate
49023-24
500 mg
¥24,600
[52785-06-5]/[1314-15-4]
PtO2
Umicore No. 68 1832 2281
※本リーフレットに記載されている製品以外にも弊社ではUmicore社製品(121品目)、Solvias社製品
(192品目)を取り扱っております。
詳細は、弊社営業所・支店までお問合わせ下さい。
【Solvias社】 化合物
(αR,αR)-2,2'-Bis(α-N,N-dimethylaminophenylmethyl)-(S,S)1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)phosphino]
ferrocene
49019-26
O
O
¥22,000
H
O
N
H
Fe
Fe
H N
Solvias No. SL-M004-1
P
49019-30
O
[494227-37-1]
N
P
100 mg
(αS,αS)-2,2'-Bis(α-N,N-dimethylaminophenylmethyl)-(R,R)1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)phosphino]
ferrocene
Solvias No. SL-M004-2
(R,S)
(S,R)
O
O
O
O
1,5-Cyclooctadiene{[dibenzyl((4R,5R)-5-methyl-2-phenyl-4,5dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite KN:KP}
iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate
49019-60
100 mg
1,5-Cyclooctadiene{[dibenzyl((4S,5S)-5-methyl-2-phenyl-4,5dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite KN:KP}
iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate
¥22,000
49019-62
[880262-14-6]
O
N
(R,R)
N
49019-82
100 mg
Solvias No. SK-X001-2a
P
(S,S)
(R)-1-[(S)-2-Di-tert-butylphosphino)ferrocenyl]
ethyldi(2-methylphenyl)phosphine
Ir(COD)(BARF)
(S)-1-[(R)-2-Di-tert-butylphosphino)ferrocenyl]
ethyldi(2-methylphenyl)phosphine
¥22,000
49019-84
[849924-76-1]
Fe
Solvias No. SL-J505-1
H CH3
¥22,000
Solvias No. SL-J505-2
(S,R)
(R,S)
(R)-1-Dicyclohexylphosphino-2-[(R)-α-(N,N-dimethylamino)o-dicyclohexylphosphinophenyl)methyl]ferrocene
49019-94
100 mg
(S)-1-Dicyclohexylphosphino-2-[(S)-α-(N,N-dimethylamino)o-dicyclohexylphosphinophenyl)methyl]ferrocene
¥22,000
49019-96
[1016985-24-2]
100 mg
¥22,000
[914089-00-2]
P
P
Solvias No. SL-T002-1
H
100 mg
[849924-77-2]
P
P
Fe
H3C H
P
P
¥22,000
O
Solvias No. SK-X001-1a
Ir(COD)(BARF)
100 mg
[583844-38-6]
O
O
P
N
¥22,000
[849925-12-8]
P
N H
P
100 mg
Fe
Solvias No. SL-T002-2
P
P
(R,R)
49020-16
CF3
H
N
(S,S)
(R)-1-[(R)-2-(2'-Dicyclohexylphosphinophenyl)ferrocenyl]
ethyldi(bis-(3,5-trifluoromethyl)phenyl)-phosphine
F3C
Fe
100 mg
(S)-1-[(S)-2-(2'-Dicyclohexylphosphinophenyl)ferrocenyl]
ethyldi(bis-(3,5-trifluoromethyl)phenyl)-phosphine
¥22,000
49020-18
F3C
CF3
[494227-32-6]
100 mg
¥22,000
CF3
[849925-22-0]
F3C
P
P
Fe
P
CH3
H
CF3
(R,R)
Solvias No. SL-W008-1
P
H3C
F3C
H
(S,S)
Fe
Solvias No. SL-W008-2
(R)-1-[(S)-2-(Di-2-furylphosphino)-ferrocenyl]
ethyldi-tert-butylphosphine
49020-24
P
CH3
Fe
¥22,000
Solvias No. SL-J212-1
H
O
(R,S)
49020-42
H3CO
P
H3C
Fe
H
100 mg
¥22,000
P
Solvias No. SL-J212-2
O
(S)-(-)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)
¥22,000
P
[133545-16-1]
P
Solvias No. SL-A101-1
49020-44
H3CO
H3CO
100 mg
¥22,000
P
[133545-17-2]
P
Solvias No. SL-A101-2
(S)
(R)
(R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]
ethyldicyclohexylphosphine ethanol adduct
49020-80
100 mg
(S)-1-[(R)-2-(Diphenylphosphino)ferrocenyl]
ethyldicyclohexylphosphine ethanol adduct
¥22,000
49020-82
[155806-35-2]
P
H
H3C
C2H5OH
C2H5OH
(R,S)
(S,R)
(R)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]
ethyldi(bis-3,5-trifluoromethylphenyl)phosphine
49020-88
CF3
CF3
F3C
100 mg
Fe
H
¥22,000
[387868-06-6]
49020-90
F3C
CF3
F3C
CH3
CF3
Solvias No. SL-W001-1
Chloro(di-2-norbornylphosphino)
(2-dimethylaminomethylferrocen-1-yl)palladium (II)
49019-58
P
F3C
H3C
Fe
H
Cl
[849925-17-3]
Solvias No. SL-W001-2
250 mg
2'-(Dimethylamino)-2-biphenylpalladium(II) chloride
dinorbornylphosphine
¥12,100
49020-62
[614753-51-4]
Pd
¥22,000
(S,S)
(R,R)
N
100 mg
P
P
H
Solvias No. SL-J001-2
P
(S)-1-[(S)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]
ethyldi(bis-3,5-trifluoromethylphenyl)phosphine
P
Fe
¥22,000
[162291-02-3]
Solvias No. SL-J001-1
CH3
Fe
100 mg
P
P
Fe
100 mg
[849924-42-1]
O
(S,R)
(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)
H3CO
49020-26
[849924-41-0]
P
O
100 mg
(S)-1-[(R)-2-(Di-2-furylphosphino)-ferrocenyl]
ethyldi-tert-butylphosphine
250 mg
¥12,100
[359803-53-5]
PH
PH
Solvias No. SK-CC02-A
Pd
N
Cl
Solvias No. SK-CC01-A
※本リーフレットに記載されている製品以外にも弊社ではUmicore社製品(121品目)、Solvias社製品
(192品目)を取り扱っております。
詳細は、弊社営業所・支店までお問合わせ下さい。
【関連製品】 Buchwald 配位子
2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl
MeO
2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl
11049-55
5g
¥35,000
11051-55
5g
¥33,000
11049-65
1g
¥11,000
11051-65
1g
¥13,000
PCy2
OMe
[564483-18-7]
[657408-07-6]
XPhos
SPhos
2-Di-tert-butylphosphino-2',4',6'-triisopropylbiphenyl
2-Dicyclohexylphosphino-2'-methylbiphenyl
11054-55
5g
¥74,000
11055-55
5g
¥52,000
11054-65
1g
¥16,000
11055-65
1g
¥12,000
[251320-86-2]
[564483-19-8]
tBuXPhos
MePhos
2-Dicyclohexylphosphino-2',6'-diisopropoxybiphenyl
11057-55
5g
¥28,000
11057-65
1g
¥11,000
2-Dicyclohexylphosphino-3,6-dimethoxy-2',4',6'triisopropylbiphenyl
MeO
OMe
11058-65
1g
¥32,000
PCy2
11058-68
100 mg
¥8,500
[787618-22-8]
[1070663-78-3]
RuPhos
BrettPhos
近日発売
2-(Di-tert-butylphosphino)biphenyl
2-Di-tert-butylphosphino-2'-(N,N-dimethylamino)
biphenyl
11059-55
5g
¥48,000
11061-55
5g
¥65,000
11059-65
1g
¥11,000
11061-65
1g
¥17,000
[224311-49-3]
[224311-51-7]
JohnPhos
tBuDavePhos
2-Di-tert-butylphosphino-3,4,5,6-tetramethyl-2',4',6'triisopropylbiphenyl
2-Di-tert-butylphosphino-2'-methylbiphenyl
11062-65
1g
¥19,000
11062-68
100 mg
¥8,000
[255837-19-5]
tBuMePhos
P(tBu)2
11063-65
1g
¥60,000
11063-68
100 mg
¥14,000
[857356-94-6]
Me4tBuXPhos
2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)
biphenyl
2-(Dicylohexylphosphino)biphenyl
11070-55
5g
¥41,000
11071-55
5g
¥60,000
11070-65
1g
¥11,000
11071-65
1g
¥16,000
PCy2
[213697-53-1]
[247940-06-3]
CyJohnPhos
2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl
DavePhos
Sodium 2'-dicyclohexylphosphino-2,6-dimethoxybiphenyl-3-sulfonate hydrate
11075-55
5g
¥44,000
38010-65
1g
¥48,000
11075-65
1g
¥15,000
38010-68
100 mg
¥11,000
[240417-00-9]
[1049726-96-6]
SPhos-SO3Na
PhDavePhos
製造元：日本化学工業株式会社
◆MITの対象特許
当該製品に関しましては、下記の通り日本国内にて出願されております。
特願2000-559117, 特願2002-583366, 特願2005-508499,
特願2007-550475, 特願2008-276608
2015.01