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Supplementary Information
J. Braz. Chem. Soc., Vol. 00, No. 00, S1-S9, 2014.
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Iridium Oxidation States in Catalytic Hydrogenation Intermediates
Janeth Navarro, Marta Martín and Eduardo Sola*
Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC - Universidad de Zaragoza,
E-50009 Zaragoza, Spain
Figure S1. 1H NMR spectrum (300.1 MHz, CD2Cl2) of compound 2.
*e-mail: [email protected]
SI
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Iridium Oxidation States in Catalytic Hydrogenation Intermediates
Figure S2. 31P{1H} NMR spectrum (121.5 MHz, CD2Cl2) of compound 2.
Figure S3. 13C{1H} NMR APT spectrum (75.5 MHz, CD2Cl2) of compound 2.
J. Braz. Chem. Soc.
Vol. 00, No. 00, 2014
Navarro et al.
Figure S4. 1H NMR spectrum (300.1 MHz, CDCl3) of compound 5.
Figure S5. 31P{1H} NMR spectrum (121.5 MHz, CDCl3) of compound 5.
Figure S6. 13C{1H} NMR APT spectrum (75.5 MHz, CDCl3) of compound 5.
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Iridium Oxidation States in Catalytic Hydrogenation Intermediates
Figure S7. 1H NMR spectrum (300.1 MHz, CD2Cl2) of compound 6 at 273 K.
Figure S8. 31P{1H} NMR spectrum (121.5 MHz, CD2Cl2) of compound 6 at 273 K.
Figure S9. 13C{1H} NMR APT spectrum (75.5 MHz, CD2Cl2) of compound 6 at 273 K.
J. Braz. Chem. Soc.
Vol. 00, No. 00, 2014
Navarro et al.
Figure S10. 1H NMR spectrum (300.1 MHz, CDCl3) of compound 7 at 273 K.
Figure S11. 31P{1H} NMR spectrum (121.5 MHz, CDCl3) of compound 7.
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Iridium Oxidation States in Catalytic Hydrogenation Intermediates
Figure S12. 13C{1H} NMR APT spectrum (75.5 MHz, CDCl3) of compound 7 at 273 K.
Figure S13. 1H NMR spectrum (300.1 MHz, CDCl3) of compound 8.
J. Braz. Chem. Soc.
Vol. 00, No. 00, 2014
Navarro et al.
Figure S14. 31P{1H} NMR spectrum (121.5 MHz, CDCl3) of compound 8.
Figure S15. 13C{1H} NMR APT spectrum (75.5 MHz, CDCl3) of compound 8.
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Iridium Oxidation States in Catalytic Hydrogenation Intermediates
Figure S16. 1H NMR spectrum (300.1 MHz, CD2Cl2) of compound 9.
Figure S17. 31P{1H} NMR spectrum (121.5 MHz, CD2Cl2) of compound 9.
J. Braz. Chem. Soc.
Vol. 00, No. 00, 2014
Navarro et al.
Figure S18. 13C{1H} NMR APT spectrum (75.5 MHz, CD2Cl2) of compound 9.
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